傅里叶红外光谱如何分析聚合物水凝胶?2025医学材料表征指南

昨天 MedSci xAi 发表于广东省
本文详解傅里叶变换红外光谱(FTIR)在聚合物水凝胶分析中的应用,解析3331cm-1(O-H)、3260cm-1(N-H)等关键特征峰的物理意义,结合聚丙烯酰胺和羧甲基纤维素钠的实际案例,提供医学材料结构表征的完整方案。

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2.2.6 Fourier Transform Infrared Spectroscopy

The absorption peaks at 3331.25 cm-1 and 1322.91667 cm-1 are attributed to O-H stretching and bending vibrations, primarily originating from free water and hydroxyl groups on the polymer chains. The absorption peak at 3260.41667 cm-1 is attributed to N-H stretching vibrations, while the peak at 1652.08333 cm-1 is attributed to C=O stretching vibrations. The absorption peak at 1447.91667 cm-1 is attributed to C-N stretching vibrations, and the peak at 560.41667 cm-1 is attributed to C-C=O bending vibrations, mainly originating from the polyacrylamide network in the system. The absorption peak at 1614.58333 cm-1 is also attributed to C=O stretching vibrations, and the peak at 1120.83333 cm-1 is attributed to C-O stretching vibrations, primarily originating from sodium carboxymethyl cellulose (Figure 3d).

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